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Gold(I)-Catalyzed Enantioselective Carboalkoxylation of Alkynes
A highly enantioselective carboalkoxylation of alkynes catalyzed by cationic (DTBM-MeO-Biphep) gold(I) complexes is reported. Various optically active beta-alkoxy indanone derivatives were obtained in good yields and high enantioselectivities. Furthermore, this methodology was extended to enantiosel...
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| Main Authors: | , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
2013
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3795527/ https://ncbi.nlm.nih.gov/pubmed/23957763 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja407150h |
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