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Gold(I)-Catalyzed Enantioselective Carboalkoxylation of Alkynes

A highly enantioselective carboalkoxylation of alkynes catalyzed by cationic (DTBM-MeO-Biphep) gold(I) complexes is reported. Various optically active beta-alkoxy indanone derivatives were obtained in good yields and high enantioselectivities. Furthermore, this methodology was extended to enantiosel...

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書目詳細資料
Main Authors: Zi, Weiwei, Toste, F. Dean
格式: Artigo
語言:Inglês
出版: 2013
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC3795527/
https://ncbi.nlm.nih.gov/pubmed/23957763
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja407150h
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