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Gold(I)-Catalyzed Enantioselective Desymmetrization of 1,3-Diols via Intramolecular Hydroalkoxylation of Allenes()

A gold(I)-catalyzed enantioselective desymmetrization of 1,3-diols was achieved via intramolecular hydroalkoxylation of allenes. The catalyst system 3-F-dppe(AuCl)(2)/(R)-C(8)-TRIPAg proved to be specifically efficient to promote the desymmetrizing cyclization of 2-aryl-1,3-diols, which have proven...

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Publicat a:Angew Chem Int Ed Engl
Autors principals: Zi, Weiwei, Toste, F. Dean
Format: Artigo
Idioma:Inglês
Publicat: 2015
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4715695/
https://ncbi.nlm.nih.gov/pubmed/26419786
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201508331
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