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Gold(I)-Catalyzed Enantioselective Desymmetrization of 1,3-Diols via Intramolecular Hydroalkoxylation of Allenes()
A gold(I)-catalyzed enantioselective desymmetrization of 1,3-diols was achieved via intramolecular hydroalkoxylation of allenes. The catalyst system 3-F-dppe(AuCl)(2)/(R)-C(8)-TRIPAg proved to be specifically efficient to promote the desymmetrizing cyclization of 2-aryl-1,3-diols, which have proven...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4715695/ https://ncbi.nlm.nih.gov/pubmed/26419786 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201508331 |
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