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Gold(I)-Catalyzed Enantioselective [4+2]-Cycloaddition of Allene-Dienes
[Image: see text] An enantioselective gold(I)-catalyzed intramolecular [4+2]-cycloaddition of allenes and dienes is reported. The reactions allows for the asymmetric synthesis of trans-hexahydroindenes and pyrrolidine products using C(3)-symmetric phosphitegold(I) and ortho-arylphosphoramiditegold(I...
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| Main Authors: | , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2010
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2798906/ https://ncbi.nlm.nih.gov/pubmed/19961192 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol902622b |
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