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Ligand-Controlled Access to [4+2] and [4+3]-Cycloadditions in Gold-Catalyzed Reactions of Allene-Dienes

[Image: see text] By adjusting the electronic properties of the ancilliary ligands high selectivity can be achieved for either gold(I)-catalyzed [4+2]- or [4+3]-cycloaddition reactions of diene-allenes. Triarylphosphitegold(I) complexes are employed as catalysts for a [4+2]-cycloaddition reactions l...

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書目詳細資料
Main Authors: Mauleón, Pablo, Zeldin, Rachel M., González, Ana Z., Toste, F. Dean
格式: Artigo
語言:Inglês
出版: 2009
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC2711638/
https://ncbi.nlm.nih.gov/pubmed/19378998
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja901649s
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