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Ligand-Controlled Access to [4+2] and [4+3]-Cycloadditions in Gold-Catalyzed Reactions of Allene-Dienes
[Image: see text] By adjusting the electronic properties of the ancilliary ligands high selectivity can be achieved for either gold(I)-catalyzed [4+2]- or [4+3]-cycloaddition reactions of diene-allenes. Triarylphosphitegold(I) complexes are employed as catalysts for a [4+2]-cycloaddition reactions l...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2711638/ https://ncbi.nlm.nih.gov/pubmed/19378998 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja901649s |
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