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On the Impact of Steric and Electronic Properties of Ligands on Gold(I)-Catalyzed Cycloaddition Reactions
[Image: see text] It is shown that [4+3] and [4+2] cycloaddition pathways are accessible in the Au(I) catalysis of allene-dienes. Seven-membered ring gold-stabilized carbenes, originating from the [4+3] cycloaddition process, are unstable and can rearrange via a 1,2-H or a 1,2-alkyl shift to yield s...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2783583/ https://ncbi.nlm.nih.gov/pubmed/19780543 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol9018002 |
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