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Mechanistic Study of Gold(I)-Catalyzed Intermolecular Hydroamination of Allenes

The intermolecular hydroamination of allenes occurs readily with hydrazide nucleophiles, in the presence of 3–12% Ph(3)PAuNTf(2). Mechanistic studies have been conducted to establish the resting state of the gold catalyst, the kinetic order of the reaction, the effect of ligand electronics on the ov...

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Main Authors: Wang, Z. Jane., Benitez, Diego, Tkatchouk, Ekaterina, Goddard, William A., Toste, F. Dean
Format: Artigo
Jezik:Inglês
Izdano: 2010
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC2939907/
https://ncbi.nlm.nih.gov/pubmed/20738092
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja105530q
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