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Mechanistic Study of Gold(I)-Catalyzed Intermolecular Hydroamination of Allenes
The intermolecular hydroamination of allenes occurs readily with hydrazide nucleophiles, in the presence of 3–12% Ph(3)PAuNTf(2). Mechanistic studies have been conducted to establish the resting state of the gold catalyst, the kinetic order of the reaction, the effect of ligand electronics on the ov...
Wedi'i Gadw mewn:
| Prif Awduron: | , , , , |
|---|---|
| Fformat: | Artigo |
| Iaith: | Inglês |
| Cyhoeddwyd: |
2010
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| Pynciau: | |
| Mynediad Ar-lein: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2939907/ https://ncbi.nlm.nih.gov/pubmed/20738092 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja105530q |
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