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Mechanistic Study of Gold(I)-Catalyzed Intermolecular Hydroamination of Allenes
The intermolecular hydroamination of allenes occurs readily with hydrazide nucleophiles, in the presence of 3–12% Ph(3)PAuNTf(2). Mechanistic studies have been conducted to establish the resting state of the gold catalyst, the kinetic order of the reaction, the effect of ligand electronics on the ov...
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| Main Authors: | , , , , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
2010
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2939907/ https://ncbi.nlm.nih.gov/pubmed/20738092 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja105530q |
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