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Gold-catalyzed intermolecular hydroamination of allenes with sulfonamides
A co-catalyst of (PPh(3))AuCl/AgOTf for the intermolecular hydroamination of allenes with sulfonamides is shown. The reaction proceeded smoothly under mild conditions for differently substituted allenes giving N-allylic sulfonamides in good yields with high regioselectivity and E-selectivity.
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| Main Authors: | , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
Beilstein-Institut
2013
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3678397/ https://ncbi.nlm.nih.gov/pubmed/23766819 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.9.117 |
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