Carregant...

Intermolecular Hydroamination of Allenes with N-Unsubstituted Carbamates Catalyzed by a Gold(I) N-Heterocyclic Carbene Complex

[Image: see text] Reaction of 2,3-pentadienyl benzoate and benzyl carbamate with a catalytic 1:1 mixture of (NHC)AuCl and AgOTf in dioxane at 23 °C for 5 h led to isolation of (E)-4-(benzyloxycarbonylamino)-2-pentenyl benzoate in 84% yield as a single regio- and diastereomer. Gold(I)-catalyzed hydro...

Descripció completa

Guardat en:
Dades bibliogràfiques
Autors principals: Kinder, Robert E., Zhang, Zhibin, Widenhoefer, Ross A.
Format: Artigo
Idioma:Inglês
Publicat: 2008
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC2727634/
https://ncbi.nlm.nih.gov/pubmed/18570376
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol8010858
Etiquetes: Afegir etiqueta
Sense etiquetes, Sigues el primer a etiquetar aquest registre!