Gold(I)-Catalyzed Stereoconvergent, Intermolecular Enantioselective Hydroamination of Allenes

[Image: see text] A 1:2 mixture of [(S)-2](AuCl)(2) [(S)-2 = (S)-3,5-t-Bu-4-MeO-MeOBIPHEP] and AgBF(4) catalyzes the stereoconvergent, intermolecular enantioselective hydroamination of chiral, racemic 1,3-disubstituted allenes with N-unsubstituted carbamates to form N-allylic carbamates in good yiel...

Full description

Saved in:
Bibliographic Details
Main Authors: Butler, Kristina L., Tragni, Michele, Widenhoefer, Ross A.
Format: Artigo
Language:Inglês
Published: 2012
Subjects:
Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3430965/
https://ncbi.nlm.nih.gov/pubmed/22492591
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201201584
Tags: Add Tag
No Tags, Be the first to tag this record!

Similar Items