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The Regio- and Stereospecific Intermolecular Dehydrative Alkoxylation of Allylic Alcohols Catalyzed by a Gold(I) N-Heterocyclic Carbene Complex

A 1:1 mixture of (IPr)AuCl [IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidine] and AgClO(4) catalyzes the intermolecular dehydrative alkoxylation of primary and secondary allylic alcohols with aliphatic primary and secondary alcohols to form allylic ethers. These transformations are regio- and...

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Detalhes bibliográficos
Main Authors: Mukherjee, Paramita, Widenhoefer, Ross A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3882269/
https://ncbi.nlm.nih.gov/pubmed/23348826
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201203987
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