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Gold(I)-Catalyzed Enantioselective Intramolecular Dehydrative Amination of Allylic Alcohols with Carbamates
A 1:2 mixture of [(S)-2](AuCl)(2) [(S)-2 = (S)-DTBM-MeOBIPHEP] and AgClO(4) catalyzes the intramolecular enantioselective dehydrative amination of allylic alcohols with carbamates to form five- and six-membered aliphatic nitrogen heterocycles in high yield with up to 95% ee.
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3429348/ https://ncbi.nlm.nih.gov/pubmed/22294357 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201107877 |
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