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Gold(I)-Catalyzed Intramolecular Amination of Allylic Alcohols With Alkylamines
[Image: see text] A 1:1 mixture of (1)AuCl [1 = P(t-Bu)(2)o-biphenyl] and AgSbF(6) catalyzes the intramolecular amination of allylic alcohols with alkylamines to form substituted pyrrolidine and piperidine derivatives. Gold(I)-catalyzed cyclization of (R,Z)-8-(N-benzylamino)-3-octen-2-ol (96% ee, 95...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3429346/ https://ncbi.nlm.nih.gov/pubmed/21314103 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol103175w |
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