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Gold(I)-Catalyzed Intramolecular Amination of Allylic Alcohols With Alkylamines

[Image: see text] A 1:1 mixture of (1)AuCl [1 = P(t-Bu)(2)o-biphenyl] and AgSbF(6) catalyzes the intramolecular amination of allylic alcohols with alkylamines to form substituted pyrrolidine and piperidine derivatives. Gold(I)-catalyzed cyclization of (R,Z)-8-(N-benzylamino)-3-octen-2-ol (96% ee, 95...

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Autori principali: Mukherjee, Paramita, Widenhoefer, Ross A.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2011
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3429346/
https://ncbi.nlm.nih.gov/pubmed/21314103
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol103175w
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