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Gold(I)-Catalyzed Intramolecular Hydroamination of N-Allylic,N′-Aryl Ureas to form Imidazolidin-2-ones

Treatment of N-allylic,N′-aryl ureas with a catalytic 1:1 mixture of di-tert-butyl-o-biphenylphoshphine gold(I) chloride and silver hexafluorophosphate (1 mol %) in chloroform at room temperature led to 5-exo hydroamination to form the corresponding imidazolidin-2-ones in excellent yield. In the cas...

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Autores principales: Li, Hao, Song, Feijie, Widenhoefer, Ross A.
Formato: Artigo
Lenguaje:Inglês
Publicado: 2011
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC3122478/
https://ncbi.nlm.nih.gov/pubmed/21709731
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/adsc.201000844
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