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Gold Catalyzed Intermolecular Markovnikov Hydroamination of Allenes with Secondary Amines
[Image: see text] A cationic (CAAC)gold(I) complex promotes the addition of all types of non-tertiary amines to a variety of allenes, affording allylic amines in good to excellent yields; the amino fragment always adds to the less substituted terminus of the CCC skeleton.
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2739117/ https://ncbi.nlm.nih.gov/pubmed/19719176 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol901418c |
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