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Gold(I)-Catalyzed Desymmetrization of 1,4-Dienes by an Enantioselective Tandem Alkoxylation/Claisen Rearrangement

An enantioselective alkoxylation/Claisen rearrangement reaction was achieved by a strategic desymmetrization of 1,4-dienes under the catalysis of (S)-DTBM-Segphos(AuCl)(2)/AgBF(4). This reaction system was highly selective for the formation of 3,3-rearrangement products, providing cycloheptenes with...

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Gorde:
Xehetasun bibliografikoak
Argitaratua izan da:Angew Chem Int Ed Engl
Egile Nagusiak: Wu, Hongmiao, Zi, Weiwei, Li, Guigen, Lu, Hongjian, Toste, F. Dean
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: 2015
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC4529066/
https://ncbi.nlm.nih.gov/pubmed/26031403
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201503357
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