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Gold(I)-Catalyzed Desymmetrization of 1,4-Dienes by an Enantioselective Tandem Alkoxylation/Claisen Rearrangement
An enantioselective alkoxylation/Claisen rearrangement reaction was achieved by a strategic desymmetrization of 1,4-dienes under the catalysis of (S)-DTBM-Segphos(AuCl)(2)/AgBF(4). This reaction system was highly selective for the formation of 3,3-rearrangement products, providing cycloheptenes with...
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| Publicado en: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2015
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4529066/ https://ncbi.nlm.nih.gov/pubmed/26031403 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201503357 |
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