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Gold(I)-Catalyzed Dearomative Rautenstrauch Rearrangement: Enantioselective Access to Cyclopenta[b]indoles

A highly enantioselective dearomative Rautenstrauch rearrangement catalyzed by cationic (S)-DTBM-Segphosgold(I) is reported. This reaction provides a straightforward method to prepare enantioenriched cyclopenta[b]indoles. These studies show vast difference in enantioselectivity in the reactions of p...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Zi, Weiwei, Wu, Hongmiao, Toste, F. Dean
Formato: Artigo
Idioma:Inglês
Publicado em: 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5087316/
https://ncbi.nlm.nih.gov/pubmed/25710515
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b00613
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