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Gold(I)-Catalyzed Enantioselective Ring Expansion of Allenylcyclopropanols

[Image: see text] The asymmetric gold(I)-catalyzed ring expansion of 1-allenylcyclopropanols is described. The method provides synthetically valuable cyclobutanones with a vinyl-substituted quaternary stereogenic center in high enantioselectivities and yields. The method shows a broad substrate scop...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Prif Awduron: Kleinbeck, Florian, Toste, F. Dean
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: 2009
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC2740622/
https://ncbi.nlm.nih.gov/pubmed/19530649
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja904055z
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