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Gold(I)-Catalyzed Enantioselective Ring Expansion of Allenylcyclopropanols
[Image: see text] The asymmetric gold(I)-catalyzed ring expansion of 1-allenylcyclopropanols is described. The method provides synthetically valuable cyclobutanones with a vinyl-substituted quaternary stereogenic center in high enantioselectivities and yields. The method shows a broad substrate scop...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2740622/ https://ncbi.nlm.nih.gov/pubmed/19530649 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja904055z |
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