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Gold(I)-Catalyzed Enantioselective [4+2]-Cycloaddition of Allene-Dienes

[Image: see text] An enantioselective gold(I)-catalyzed intramolecular [4+2]-cycloaddition of allenes and dienes is reported. The reactions allows for the asymmetric synthesis of trans-hexahydroindenes and pyrrolidine products using C(3)-symmetric phosphitegold(I) and ortho-arylphosphoramiditegold(I...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Prif Awduron: González, Ana Z., Toste, F. Dean
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: 2010
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC2798906/
https://ncbi.nlm.nih.gov/pubmed/19961192
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol902622b
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