Tetranuclear [Mn(III)Mn(3)(IV)O(4)] Complexes as Spectroscopic Models of the S(2) State of the Oxygen Evolving Complex in Photosystem II

Despite extensive biochemical, spectroscopic, and computational studies, the mechanism of biological water oxidation by the Oxygen Evolving Complex (OEC) of Photosystem II remains a subject of significant debate. Mechanistic proposals are guided by the characterization of reaction intermediates such...

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Pubblicato in:J Am Chem Soc
Autori principali: Lee, Heui Beom, Shiau, Angela A., Oyala, Paul H., Marchiori, David A., Gul, Sheraz, Chatterjee, Ruchira, Yano, Junko, Britt, R. David, Agapie, Theodor
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2018
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Article
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6574184/
https://ncbi.nlm.nih.gov/pubmed/30407806
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b09961
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