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High-spin Mn–oxo complexes and their relevance to the oxygen-evolving complex within photosystem II

The structural and electronic properties of a series of manganese complexes with terminal oxido ligands are described. The complexes span three different oxidation states at the manganese center (III–V), have similar molecular structures, and contain intramolecular hydrogen-bonding networks surround...

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Detalhes bibliográficos
Publicado no:Proc Natl Acad Sci U S A
Main Authors: Gupta, Rupal, Taguchi, Taketo, Lassalle-Kaiser, Benedikt, Bominaar, Emile L., Yano, Junko, Hendrich, Michael P., Borovik, A. S.
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4418911/
https://ncbi.nlm.nih.gov/pubmed/25852147
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1422800112
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