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Characterization of Monomeric Mn(II/III/IV)–Hydroxo Complexes from X- and Q-Band Dual Mode Electron Paramagnetic Resonance (EPR) Spectroscopy

Manganese–hydroxo species have been implicated in C–H bond activation performed by metalloenzymes, but the electronic properties of many of these intermediates are not well characterized. The present work presents a detailed characterization of three Mn(n)–OH complexes (where n = II, III, and IV) of...

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Detalhes bibliográficos
Main Authors: Gupta, Rupal, Taguchi, Taketo, Borovik, A. S., Hendrich, Michael P.
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3878184/
https://ncbi.nlm.nih.gov/pubmed/24156406
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic401681r
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