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Preparation and Properties of a Monomeric High-Spin Mn(V)–Oxo Complex

Oxomanganese(V) species have been implicated in a variety of biological and synthetic processes, including as a key reactive center within the oxygen-evolving complex in photosynthesis. Nearly all mononuclear Mn(V)–oxo complexes have tetragonal symmetry, producing low-spin species. A new Mn(V)–oxo c...

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Detalhes bibliográficos
Main Authors: Taguchi, Taketo, Gupta, Rupal, Lassalle-Kaiser, Benedikt, Boyce, David W., Yachandra, Vittal K., Tolman, William B., Yano, Junko, Hendrich, Michael P., Borovik, A.S.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3390030/
https://ncbi.nlm.nih.gov/pubmed/22233169
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja210957u
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