Activation of a water molecule using a mononuclear Mn complex: from Mn-aquo, to Mn-hydroxo, to Mn-oxyl via charge compensation()

Activation of a water molecule by the electrochemical oxidation of a Mn-aquo complex accompanied by the loss of protons is reported. The sequential (2 × 1 electron/1 proton) and direct (2 electron/2 proton) proton-coupled electrochemical oxidation of a non-porphyrinic six-coordinated Mn(II)OH(2) com...

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Detalhes bibliográficos
Main Authors: Lassalle-Kaiser, Benedikt, Hureau, Christelle, Pantazis, Dimitrios A., Pushkar, Yulia, Guillot, Régis, Yachandra, Vittal K., Yano, Junko, Neese, Frank, Anxolabéhère-Mallart, Elodie
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3997265/
https://ncbi.nlm.nih.gov/pubmed/24772190
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/B926990H
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