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Single Crystal X- and Q-Band EPR Spectroscopy of a Binuclear Mn(2)(III,IV) Complex Relevant to the Oxygen-Evolving Complex of Photosystem II

The anisotropic g and hyperfine tensors of the Mn di-μ-oxo complex, [Mn(2)(III,IV)O(2)(phen)(4)](PF(6))(3)·CH(3)CN, were derived by single-crystal EPR measurements at X- and Q-band frequencies. This is the first simulation of EPR parameters from single-crystal EPR spectra for multinuclear Mn complex...

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Dettagli Bibliografici
Autori principali: Yano, Junko, Sauer, Kenneth, Girerd, Jean-Jacques, Yachandra, Vittal K.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2004
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3960403/
https://ncbi.nlm.nih.gov/pubmed/15198595
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja038218j
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