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Single Crystal X- and Q-Band EPR Spectroscopy of a Binuclear Mn(2)(III,IV) Complex Relevant to the Oxygen-Evolving Complex of Photosystem II
The anisotropic g and hyperfine tensors of the Mn di-μ-oxo complex, [Mn(2)(III,IV)O(2)(phen)(4)](PF(6))(3)·CH(3)CN, were derived by single-crystal EPR measurements at X- and Q-band frequencies. This is the first simulation of EPR parameters from single-crystal EPR spectra for multinuclear Mn complex...
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| Main Authors: | , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2004
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3960403/ https://ncbi.nlm.nih.gov/pubmed/15198595 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja038218j |
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