CaMn(3)(IV)O(4) Cubane Models of the Oxygen Evolving Complex: Spin Ground States S < 9/2 and the Effect of Oxo Protonation

We report single crystal XRD and MicroED structure, magnetic susceptibility, and EPR data of a series of CaMn(3)(IV)O(4) and YMn(3)(IV)O(4) complexes as structural and spectroscopic models of the cuboidal subunit of the OEC. The effect of changes in heterometal identity, cluster geometry, and bridgi...

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Publicado en:Angew Chem Int Ed Engl
Autores principales: Lee, Heui Beom, Shiau, Angela A., Marchiori, David A., Oyala, Paul H., Yoo, Byung-Kuk, Kaiser, Jens T., Rees, Douglas C., Britt, R. David, Agapie, Theodor
Formato: Artigo
Lenguaje:Inglês
Publicado: 2021
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Article
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC8319083/
https://ncbi.nlm.nih.gov/pubmed/34042234
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202105303
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