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S = 3 Ground State for a Tetranuclear Mn(IV)(4)O(4) Complex Mimicking the S(3) state of the Oxygen Evolving Complex

The S(3) state is currently the last observable intermediate prior to O–O bond formation at the oxygen evolving complex (OEC) of Photosystem II, and its electronic structure has been assigned to a homovalent Mn(IV)(4) core with an S = 3 ground state. While structural interpretations based on the EPR...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Lee, Heui Beom, Marchiori, David A., Chatterjee, Ruchira, Oyala, Paul H., Yano, Junko, Britt, R. David, Agapie, Theodor
Formato: Artigo
Idioma:Inglês
Publicado em: 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7236085/
https://ncbi.nlm.nih.gov/pubmed/32013412
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b10371
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