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CaMn(4)O(2) model of the biological Oxygen Evolving Complex: Synthesis by cluster expansion on low symmetry ligand
Using a new multinucleating ligand featuring two dipyridylalkoxide and a carboxylate moiety, low symmetry tetranuclear complexes 1-M (M = Mn, Fe, and Co) have been synthesized. Complex 1-Mn was used as precursor for the synthesis of a pentanuclear CaMn(4)O(2) cluster (3) with the same metal stoichio...
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| Publicat a: | Chem Commun (Camb) |
|---|---|
| Autors principals: | , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2017
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5508601/ https://ncbi.nlm.nih.gov/pubmed/28480467 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7cc02313h |
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