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CaMn(4)O(2) model of the biological Oxygen Evolving Complex: Synthesis by cluster expansion on low symmetry ligand
Using a new multinucleating ligand featuring two dipyridylalkoxide and a carboxylate moiety, low symmetry tetranuclear complexes 1-M (M = Mn, Fe, and Co) have been synthesized. Complex 1-Mn was used as precursor for the synthesis of a pentanuclear CaMn(4)O(2) cluster (3) with the same metal stoichio...
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| Publicado no: | Chem Commun (Camb) |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5508601/ https://ncbi.nlm.nih.gov/pubmed/28480467 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7cc02313h |
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