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Thermodynamics of Proton and Electron Transfer in Tetranuclear Clusters with Mn–OH(2)/OH Motifs Relevant to H(2)O Activation by the Oxygen Evolving Complex in Photosystem II
We report the synthesis of site-differentiated heterometallic clusters with three Fe centers and a single Mn site that binds water and hydroxide in multiple cluster oxidation states. Deprotonation of Fe(III/II)(3)Mn(II)–OH(2) clusters leads to internal reorganization resulting in formal oxidation at...
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| Gepubliceerd in: | J Am Chem Soc |
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| Hoofdauteurs: | , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
2018
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| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6277146/ https://ncbi.nlm.nih.gov/pubmed/30064207 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b06426 |
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