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Intermolecular Hydroamination of 1,3-Dienes to Generate Homoallylic Amines
We report a Rh-catalyzed hydroamination of 1,3-dienes to generate homoallylic amines. Our work showcases the first case of anti-Markovnikov selectivity in the intermolecular coupling of amines and 1,3-dienes. By tuning the ligand properties and Brensted acid additive, we find that a combination of r...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6563820/ https://ncbi.nlm.nih.gov/pubmed/28953374 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b09188 |
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