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Enantioselective Intermolecular Pd-Catalyzed Hydroalkylation of Acyclic 1,3-Dienes with Activated Pronucleophiles
We report a highly enantioselective Pd−PHOX-catalyzed intermolecular hydroalkylation of acyclic 1,3-dienes. Meldrum’s acid derivatives and other activated C-pronucleophiles, such as β-diketones and malononitriles, react with a variety of aryl- and alkyl-substituted dienes in ≤20 h at room temperatur...
Sparad:
| I publikationen: | J Am Chem Soc |
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| Huvudupphovsmän: | , , |
| Materialtyp: | Artigo |
| Språk: | Inglês |
| Publicerad: |
2018
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| Ämnen: | |
| Länkar: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5937024/ https://ncbi.nlm.nih.gov/pubmed/29446922 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b13300 |
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