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Enantioselective Intermolecular Pd-Catalyzed Hydroalkylation of Acyclic 1,3-Dienes with Activated Pronucleophiles

We report a highly enantioselective Pd−PHOX-catalyzed intermolecular hydroalkylation of acyclic 1,3-dienes. Meldrum’s acid derivatives and other activated C-pronucleophiles, such as β-diketones and malononitriles, react with a variety of aryl- and alkyl-substituted dienes in ≤20 h at room temperatur...

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Bibliografiska uppgifter
I publikationen:J Am Chem Soc
Huvudupphovsmän: Adamson, Nathan J., Wilbur, Katherine C. E., Malcolmson, Steven J.
Materialtyp: Artigo
Språk:Inglês
Publicerad: 2018
Ämnen:
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC5937024/
https://ncbi.nlm.nih.gov/pubmed/29446922
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b13300
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