Loading...

Enantioselective Intermolecular Addition of Aliphatic Amines to Acyclic Dienes with a Pd–PHOX Catalyst

We report a method for the catalytic, enantioselective intermolecular addition of aliphatic amines to acyclic 1,3-dienes. In most cases, reactions proceed efficiently at or below room temperature in the presence of 5 mol % of a Pd catalyst bearing a PHOX ligand, generating allylic amines in up to 97...

Fuld beskrivelse

Na minha lista:
Bibliografiske detaljer
Udgivet i:J Am Chem Soc
Main Authors: Adamson, Nathan J., Hull, Ethan, Malcolmson, Steven J.
Format: Artigo
Sprog:Inglês
Udgivet: 2017
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5937019/
https://ncbi.nlm.nih.gov/pubmed/28453290
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b03480
Tags: Tilføj Tag
Ingen Tags, Vær først til at tagge denne postø!