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Scandium-catalysed intermolecular hydroaminoalkylation of olefins with aliphatic tertiary amines

A homoleptic scandium trialkyl complex in combination with a borate compound served as an excellent catalyst for the C–H addition of aliphatic tertiary amines to olefins. This highly regiospecific, 100% atom efficient C–H bond alkylation reaction was applicable to a wide variety of tertiary amines a...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Nako, Adi E., Oyamada, Juzo, Nishiura, Masayoshi, Hou, Zhaomin
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5356020/
https://ncbi.nlm.nih.gov/pubmed/28451099
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc02129h
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