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Regioselective Hydroacylation of 1,3-Dienes by Cobalt Catalysis
[Image: see text] We describe a cobalt-catalyzed hydroacylation of 1,3-dienes with non-chelating aldehydes. Aromatic aldehydes provide 1,4-addition products as the major isomer, while aliphatic aldehydes favor 1,2-hydroacylation products. The kinetic profile supports an oxidative cyclization mechani...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical
Society
2014
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4117386/ https://ncbi.nlm.nih.gov/pubmed/24588202 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja500268w |
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