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Effect of proximal ligand substitutions on the carbene and nitrene transferase activity of myoglobin

Engineered myoglobins were recently shown to be effective catalysts for abiological carbene and nitrene transfer reactions. Here, we investigated the impact of substituting the conserved heme-coordinating histidine residue with both proteinogenic (Cys, Ser, Tyr, Asp) and non-proteinogenic Lewis basi...

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Vydáno v:Tetrahedron
Hlavní autoři: Moore, Eric J., Fasan, Rudi
Médium: Artigo
Jazyk:Inglês
Vydáno: 2019
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6534480/
https://ncbi.nlm.nih.gov/pubmed/31133770
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2019.03.009
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