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Cyclopropanations via Heme Carbenes: Basic Mechanism and Effects of Carbene Substituent, Protein Axial Ligand, and Porphyrin Substitution
[Image: see text] Catalytic carbene transfer to olefins is a useful approach to synthesize cyclopropanes, which are key structural motifs in many drugs and biologically active natural products. While catalytic methods for olefin cyclopropanation have largely relied on rare transition-metal-based cat...
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| Udgivet i: | J Am Chem Soc |
|---|---|
| Main Authors: | , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
American Chemical
Society
2017
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| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5875692/ https://ncbi.nlm.nih.gov/pubmed/29268614 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b09171 |
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