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Catalytic and Biocatalytic Iron Porphyrin Carbene Formation: Effects of Binding Mode, Carbene Substituent, Porphyrin Substituent, and Protein Axial Ligand
[Image: see text] Iron porphyrin carbenes (IPCs) are important intermediates in various chemical reactions catalyzed by iron porphyrins and engineered heme proteins, as well as in the metabolism of various xenobiotics by cytochrome P450. However, there are no prior theoretical reports to help unders...
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| Published in: | J Am Chem Soc |
|---|---|
| Main Authors: | , |
| Format: | Artigo |
| Language: | Inglês |
| Published: |
American Chemical
Society
2015
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| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4482416/ https://ncbi.nlm.nih.gov/pubmed/26067900 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b03437 |
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