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Catalytic iron-carbene intermediate revealed in a cytochrome c carbene transferase
Recently, heme proteins have been discovered and engineered by directed evolution to catalyze chemical transformations that are biochemically unprecedented. Many of these nonnatural enzyme-catalyzed reactions are assumed to proceed through a catalytic iron porphyrin carbene (IPC) intermediate, altho...
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| Publicado no: | Proc Natl Acad Sci U S A |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6048479/ https://ncbi.nlm.nih.gov/pubmed/29946033 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1807027115 |
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