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Effect of proximal ligand substitutions on the carbene and nitrene transferase activity of myoglobin

Engineered myoglobins were recently shown to be effective catalysts for abiological carbene and nitrene transfer reactions. Here, we investigated the impact of substituting the conserved heme-coordinating histidine residue with both proteinogenic (Cys, Ser, Tyr, Asp) and non-proteinogenic Lewis basi...

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Detalhes bibliográficos
Publicado no:Tetrahedron
Main Authors: Moore, Eric J., Fasan, Rudi
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6534480/
https://ncbi.nlm.nih.gov/pubmed/31133770
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2019.03.009
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