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Effect of proximal ligand substitutions on the carbene and nitrene transferase activity of myoglobin

Engineered myoglobins were recently shown to be effective catalysts for abiological carbene and nitrene transfer reactions. Here, we investigated the impact of substituting the conserved heme-coordinating histidine residue with both proteinogenic (Cys, Ser, Tyr, Asp) and non-proteinogenic Lewis basi...

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Bibliografische gegevens
Gepubliceerd in:Tetrahedron
Hoofdauteurs: Moore, Eric J., Fasan, Rudi
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: 2019
Onderwerpen:
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6534480/
https://ncbi.nlm.nih.gov/pubmed/31133770
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2019.03.009
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