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Chemoselective Cyclopropanation over Carbene Y—H insertion Catalyzed by an Engineered Carbene Transferase

Hemoproteins have recently emerged as promising biocatalysts for promoting a variety of carbene transfer reactions including cyclopropanation and Y—H insertion (Y = N, S, Si, B). For these and synthetic carbene transfer catalysts alike, achieving high chemoselectivity toward cyclopropanation in olef...

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Dades bibliogràfiques
Publicat a:J Org Chem
Autors principals: Moore, Eric J., Steck, Viktoria, Bajaj, Priyanka, Fasan, Rudi
Format: Artigo
Idioma:Inglês
Publicat: 2018
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6291643/
https://ncbi.nlm.nih.gov/pubmed/29905476
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.8b00946
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