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Origin of high stereocontrol in olefin cyclopropanation catalyzed by an engineered carbene transferase
Recent advances in metalloprotein engineering have led to the development of a myoglobin-based catalyst, Mb(H64V,V68A), capable of promoting the cyclopropanation of vinylarenes with high efficiency and high diastereo- and enantioselectivity. Whereas many enzymes evolved in nature often exhibit catal...
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| Publicado en: | ACS Catal |
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| Autores principales: | , , , , , , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2018
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6534153/ https://ncbi.nlm.nih.gov/pubmed/31134138 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.8b04073 |
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