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Highly diastereo- and enantioselective synthesis of trifluoromethyl-substituted cyclopropanes via myoglobin-catalyzed transfer of trifluoromethylcarbene
We report on an efficient strategy for the asymmetric synthesis of trifluoromethyl-substituted cyclopropanes by means of myoglobin-catalyzed olefin cyclopropanation reactions in the presence of 2-diazo-1,1,1-trifluoroethane (CF(3)CHN(2)) as the carbene donor. These transformations were realized usin...
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| Publicat a: | J Am Chem Soc |
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| Autors principals: | , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2017
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5755966/ https://ncbi.nlm.nih.gov/pubmed/28366001 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b00768 |
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