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An Aminoimidazole Radical Intermediate in the Anaerobic Biosynthesis of the 5,6-dimethylbenzimidazole Ligand to Vitamin B12

Organisms that perform the de novo biosynthesis of cobalamin (vitamin B12) do so via unique pathways depending on the presence of oxygen in the environment. The anaerobic biosynthesis pathway of 5,6-dimethylbenzimidazole, the so-called “lower ligand” to the cobalt center, has been recently identifie...

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Dettagli Bibliografici
Pubblicato in:J Am Chem Soc
Autori principali: Gagnon, Derek M., Stich, Troy A., Mehta, Angad P., Abdelwahed, Sameh H., Begley, Tadhg P., Britt, R. David
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2018
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6435355/
https://ncbi.nlm.nih.gov/pubmed/30208703
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b05686
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