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An Aminoimidazole Radical Intermediate in the Anaerobic Biosynthesis of the 5,6-dimethylbenzimidazole Ligand to Vitamin B12

Organisms that perform the de novo biosynthesis of cobalamin (vitamin B12) do so via unique pathways depending on the presence of oxygen in the environment. The anaerobic biosynthesis pathway of 5,6-dimethylbenzimidazole, the so-called “lower ligand” to the cobalt center, has been recently identifie...

詳細記述

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書誌詳細
出版年:J Am Chem Soc
主要な著者: Gagnon, Derek M., Stich, Troy A., Mehta, Angad P., Abdelwahed, Sameh H., Begley, Tadhg P., Britt, R. David
フォーマット: Artigo
言語:Inglês
出版事項: 2018
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC6435355/
https://ncbi.nlm.nih.gov/pubmed/30208703
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b05686
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