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Anaerobic 5-Hydroxylbenzimidazole formation from aminoimidazole ribotide: an unanticipated intersection of thiamin and vitamin B(12) biosynthesis
Comparative genomics of the bacterial thiamin pyrimidine synthase (thiC) revealed a paralog of thiC (bzaF) clustered with anaerobic vitamin B(12) biosynthetic genes. Here we demonstrate that BzaF is a radical S-adenosylmethionine enzyme that catalyzes the remarkable conversion of aminoimidazole ribo...
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| Publié dans: | J Am Chem Soc |
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| Auteurs principaux: | , , , , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2015
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4753784/ https://ncbi.nlm.nih.gov/pubmed/26237670 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b03576 |
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