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Synthetic Designs and Structural Investigations of Biomimetic Ni-Fe Thiolates
Described are the syntheses of several Ni(μ-SR)(2)Fe complexes, including hydride derivatives, in a search for improved models for the active site of [NiFe]-hydrogenases. The nickel(II) precursors include (i) nickel with tripodal ligands: Ni(PS(3))(−) and Ni(NS(3))(−) (PS(3)(3-) = tris(phenyl-2-thio...
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| Publicado no: | Inorg Chem |
|---|---|
| Main Authors: | , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6379113/ https://ncbi.nlm.nih.gov/pubmed/30707014 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.8b02991 |
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