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Electron-Rich, Diiron Bis(monothiolato) Carbonyls: C–S Bond Homolysis in a Mixed Valence Diiron Dithiolate
The synthesis and redox properties are presented for the electron-rich bis(monothiolate)s Fe(2)(SR)(2)-(CO)(2)(dppv)(2) for R = Me ([1](0)), Ph ([2](0)), CH(2)Ph ([3](0)). Whereas related derivatives adopt C(2)-symmetric Fe(2)(CO)(2)P(4) cores, [1](0)–[3](0) have C(s) symmetry resulting from the uns...
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| Publicado no: | Inorg Chem |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5927630/ https://ncbi.nlm.nih.gov/pubmed/29620876 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.8b00094 |
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