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Hydrogen Activation by Biomimetic Diiron Dithiolates
Using the thermally stable salts of [Fe(2)(SR)(2)(CO)(3)(PMe(3))(dppv)]BAr(F)(4), we found that the azadithiolates [Fe(2)(adtR)(CO)(3)(PMe(3))(dppv)](+) react with high pressures of H(2) to give the hydride [(μ-H)Fe(2)(adt)(CO)(3)(PMe(3))(dppv)]BAr(F)(4). The related oxadithiolate and propanedithiol...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2737088/ https://ncbi.nlm.nih.gov/pubmed/19603776 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic900850u |
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