Nitrosyl Derivatives of Diiron(I) Dithiolates Mimic the Structure and Lewis Acidity of the FeFe-Hydrogenase Active Site

This study probes the impact of electronic asymmetry of diiron(I) dithiolato carbonyls. Treatment of Fe(2)(S(2)C(n)H(2n))(CO)(6-x)(PMe(3))(x) compounds (n = 2, 3) with NOBF(4) gave the derivatives [Fe(2)(S(2)C(n)H(2n))(CO)(5-x)(PMe(3))(x)(NO)]BF(4) (x = 1, 2, 3) which are electronically unsymmetrica...

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Detaylı Bibliyografya
Asıl Yazarlar: Olsen, Matthew T., Bruschi, Maurizio, De Gioia, Luca, Rauchfuss, Thomas B., Wilson, Scott R.
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: 2008
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Article
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC2574744/
https://ncbi.nlm.nih.gov/pubmed/18700771
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja802268p
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