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Nitrosyl Derivatives of Diiron(I) Dithiolates Mimic the Structure and Lewis Acidity of the FeFe-Hydrogenase Active Site
This study probes the impact of electronic asymmetry of diiron(I) dithiolato carbonyls. Treatment of Fe(2)(S(2)C(n)H(2n))(CO)(6-x)(PMe(3))(x) compounds (n = 2, 3) with NOBF(4) gave the derivatives [Fe(2)(S(2)C(n)H(2n))(CO)(5-x)(PMe(3))(x)(NO)]BF(4) (x = 1, 2, 3) which are electronically unsymmetrica...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2574744/ https://ncbi.nlm.nih.gov/pubmed/18700771 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja802268p |
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